Rules for the Transport of Dangerous Goods in Containers (ADR, IMDG)

19. 5. 2025

Transport of dangerous goods in containers represents a crucial area of global logistics, where safety, precision, and knowledge of regulations are key. Rules for containers with dangerous goods are based on international agreements and codes, in particular:

  • ADR – European Agreement concerning the International Carriage of Dangerous Goods by Road
  • IMDG Code – International Maritime Code for the Transport of Dangerous Goods

These regulations ensure that chemicals, gases, explosives, and other hazardous materials are transported with maximum protection of human health, property, and the environment.

Basic Principles of Dangerous Goods Transport Regulation

What is Dangerous Goods?

Dangerous goods (English: Dangerous Goods, DG or Hazmat) is any substance, mixture, or object that can cause by its properties:

  • Explosion, fire, toxic exposure
  • Corrosion, infection, radioactive contamination
  • Environmental damage

Classification and regulation is governed by the UN “Orange Book” – UN Recommendations on the Transport of Dangerous Goods – Model Regulations, which provides a unified system for:

Regulation ElementDescription
ClassificationClassifies substances into 9 classes according to primary hazard
UN NumberUnique four-digit number for each dangerous substance/group
Official Name (PSN)Standardized name for transport
Packing Group (PG)Degree of hazard: I (high), II (medium), III (low)
Marking and LabelsSafety pictograms, warning labels, placards
Transport DocumentsMandatory documentation for all transport modes

Classification of Dangerous Goods: 9 Classes

Each dangerous substance is classified into one of these classes:

ClassNameExample Substance/ItemKey Risk
1ExplosivesExplosives, pyrotechnics, ammunitionExplosion, detonation
2GasesPropane, acetylene, oxygen, chlorineFlammability, toxicity
3Flammable LiquidsGasoline, ethanol, paintsCombustion, vapors
4Flammable SolidsSulfur, white phosphorus, carbideSelf-ignition, gas evolution
5Oxidizing SubstancesAmmonium nitrate, organic peroxidesOxidation, reaction
6Toxic/Infectious SubstancesCyanides, pesticides, biological samplesPoisoning, infection
7Radioactive MaterialsMedical isotopes, uraniumRadiation
8CorrosivesSulfuric acid, sodium hydroxideCorrosion, erosion
9Miscellaneous Hazardous SubstancesLithium batteries, asbestos, environmental hazardsVarious

These classes determine the method of packing, marking, storage, and response in case of accident.

Identification, Packing, and Marking

Each shipment of dangerous goods must be clearly identified and properly packed. Key elements:

UN Number

  • Four-digit number (e.g., UN 1203 – gasoline)
  • Stated on packages, documents, and containers

Official Name for Transport (PSN)

  • Exact name according to UN Model Regulations (e.g., PETROL)
  • Must be consistent on all documents and markings

Packing Group (Packing Group – PG)

  • Determines the resistance of packaging against substance risk
  • I – high risk, II – medium, III – lower

UN Certified Packages

  • Packages must be tested and approved for specific class and PG
  • Marking: e.g., “UN 4G/Y30/S/22/D/BAM1234”

Safety Labels and Placards

  • Diamond labels (100×100 mm) on individual items
  • Large safety placards (min. 250×250 mm) on container

Specifics of Container Transport According to ADR

Basic ADR Requirements

  • Applies to road transport in Europe and neighboring countries
  • Consists of the ADR Agreement and two annexes (A – substances, B – vehicles, crew)

Container Marking According to ADR

ElementDimensionsLocationSpecifics
Orange Plates400×300 mmFront and rear of vehicleReflective, black border 15 mm, fire resistance 15 min
Reduced Plates300×120 mmFront of smaller vehiclesBlack border 10 mm
Large Safety Marks250×250 mmBoth sides and both ends of containerSame symbol as on packaging inside, may also be 100×100 mm for small items
Identification Numbers100 mm heightOrange plates when transporting loose substancesUpper part – hazard code, lower – UN number, separated by line

Exceptions apply to certain substances (e.g., class 1.4S, class 7).

Special Marking for Limited Quantities (LQ):

  • Square at top (min. 250×250 mm), upper and lower corners blackened
  • Mandatory for shipments >8 tons gross weight and permitted weight >12 tons

Documentation

  • ADR Transport Document (contains UN number, PSN, class, PG, quantity, sender/recipient)
  • Written Instructions for Accidents (must be in vehicle)
  • Driver must have valid ADR training

Cargo Securing

  • Cargo must be properly secured to prevent movement or damage
  • Obligation to segregate incompatible substances according to ADR tables

IMDG Code Requirements for Container Transport

Introduction to IMDG Code

Hazard Classes (IMDG)

  • Same classification as ADR (see above)
  • Specifics for certain classes: for example, high requirements for stowing explosives, segregation of peroxides, classification of lithium batteries (UN3481, UN3171)

Key Requirements for Containers

RequirementDescription
Container MarkingLarge safety placards (placards) min. 250×250 mm on all 4 sides of container
DocumentationMultimodal Dangerous Goods Form (shipper’s declaration that shipment complies with IMDG Code)
Container Packing Certificate (CPC)Confirmation by the person who packed the container that all requirements for cleanliness, segregation, and packing were met
Stowing and SegregationPrecise rules for placement on deck, separation from other classes or living quarters
Crew TrainingMandatory training according to STCW and IMO; knowledge of marks, handling, response to incidents
Container CertificationOnly approved and undamaged containers used, visual inspection before loading

IMDG Code Compliance

  • Emphasis on package integrity and prevention of contact between incompatible substances
  • Special marking and classification for fuel cells, battery vehicles, lithium batteries

Penalties for Non-Compliance

  • Fines according to PHMSA regulations (in the USA up to $224,755 in case of serious violation)
  • In Europe, penalties according to national legislation and international regulations (shipment detention, fines, transport ban)

Multimodal Transport and Related Regulations

Air Transport (IATA DGR)

  • Based on ICAO Technical Instructions
  • Highest requirements for packing, quantity, and marking
  • Shipments prepared for air transport must also meet IMDG/ADR requirements for further transport

Rail Transport (RID)

  • Analogous requirements for classification, marking, documentation as ADR

Important: Each participant in the transport chain (shipper, packing person, carrier, recipient) must know and apply all relevant regulations.

Practical Procedure for Sending Dangerous Goods in a Container

Step-by-Step Procedure

  1. Classification and Identification of Goods
  • Determination of class, UN number, PSN, and PG (according to safety sheet/MSDS)
  1. Selection and Preparation of Packaging
  • Approved UN package, marked with UN code, correct labels
  1. Preparation of Documentation
  • ADR document for road / Multimodal Dangerous Goods Form for sea
  • Container Packing Certificate
  1. Loading and Securing in Container
  • Check cleanliness, container integrity
  • Securing and segregation of cargo according to regulations
  1. Container Marking
  • Safety placards on all 4 sides, possibly identification numbers
  1. Handover to Carrier
  • Container and documentation receipt, verification of all requirements compliance

Key Roles

RoleResponsibility
ShipperClassification, packing, marking, documentation
Packing PersonProper loading, securing, segregation, CPC signature
CarrierVerification of marking, documentation, staff training, use of suitable vehicle/vessel
RecipientTimely receipt and unloading, integrity check

All workers must be trained according to their activity. Training is mandatory and regularly renewed according to legislation.

Technical Requirements for Container Marking

Table – Overview of Marking

Type of MarkingDimensions (mm)Surface TreatmentLocation on Container/VehicleSpecifics
Orange Plate ADR400×300Reflective, black border 15 mmFront and rear of vehicleIdentification numbers when transporting loose substances
Safety Placard250×250Durable material4 sides of containerSymbol according to class
LQ Label (Limited Quantity)250×250Square at top4 sides of container for shipments >8t/12tUpper and lower corners blackened

Most Common Errors and Risks

  • Incorrect Classification of Goods – leads to dangerous reactions during accident or inspection.
  • Missing/Damaged Marking – risk of shipment detention, penalties, or accident.
  • Insufficient Cargo Securing – risk of shifting, leakage, container/ship damage.
  • Missing or Incorrect Documentation – fines, detention, transport ban.
  • Insufficient Staff Training – increased risk of errors during handling.


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